Phosphine-Catalyzed Intramolecular Vinylogous Aldol Reaction of α-Substituted Enones

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DC Field	Value	Language
dc.contributor.author	Mondal, Atanu	-
dc.contributor.author	Satpathi, Bishnupada	-
dc.contributor.author	Ramasastry, S. S. V.	-
dc.date.accessioned	2023-08-19T13:01:48Z	-
dc.date.available	2023-08-19T13:01:48Z	-
dc.date.issued	2022	-
dc.identifier.citation	Organic Letters, 24(1), 256-261.	en_US
dc.identifier.uri	https://doi.org/10.1021/acs.orglett.1c03913	-
dc.identifier.uri	http://hdl.handle.net/123456789/4907	-
dc.description	Only IISER Mohali authors are available in the record.	en_US
dc.description.abstract	We demonstrate the first phosphine-catalyzed intramolecular vinylogous aldol reaction (IVAR) of α-substituted enones. This strategy provides access to various pentannulated (hetero)arenes and dibenzocycloheptanones incorporated with two contiguous stereocenters, one of which is an all-carbon quaternary center. The scope of this work is further broadened through elaborations of the IVAR adducts to (i) benzannulated nine-membered carbocyclic systems, (ii) interesting classes of 1,3-dienes, 1,3,5-trienes, and 1-yn-3,5-dienes, and (iii) the analogs of echinolactone D and russujaponol F.	en_US
dc.language.iso	en_US	en_US
dc.publisher	ACS Publications	en_US
dc.subject	Phosphine-Catalyzed	en_US
dc.subject	Intramolecular Vinylogous	en_US
dc.subject	Aldol Reaction of α-Substituted Enones	en_US
dc.title	Phosphine-Catalyzed Intramolecular Vinylogous Aldol Reaction of α-Substituted Enones	en_US
dc.type	Article	en_US
Appears in Collections:	Research Articles

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