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http://hdl.handle.net/123456789/4909| Title: | Pd-Catalyzed Nazarov-Type Cyclization: Application in the Total Synthesis of β-Diasarone and Other Complex Cyclopentanoids |
| Authors: | Singh, Bara Bankar, Siddheshwar K. Ramasastry, S. S. V. |
| Keywords: | Pd-Catalyzed Nazarov-Type Cyclization Total Synthesis of β-Diasarone Complex Cyclopentanoids |
| Issue Date: | 2022 |
| Publisher: | ACS Publications |
| Citation: | Organic Letters, 24(4), 1043-1048. |
| Abstract: | We describe the palladium-catalyzed Nazarov-type cyclization of easily accessible (hetero)arylallyl acetates to pentannulated (hetero)arenes. This method provides ready access to various types of bi-, tri-, tetra-, and pentacyclic cyclopentanoids under neutral conditions. The synthetic utility is further demonstrated in the first total synthesis of β-diasarone and several other complex cyclopentanoids relevant to medicinal chemistry and materials science. |
| Description: | Only IISER Mohali authors are available in the record. |
| URI: | https://doi.org/10.1021/acs.orglett.1c04243 http://hdl.handle.net/123456789/4909 |
| Appears in Collections: | Research Articles |
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