Please use this identifier to cite or link to this item: http://hdl.handle.net/123456789/4928
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dc.contributor.authorGupta, Debapriya-
dc.contributor.authorGaur, Ankit Kumar-
dc.contributor.authorKumar, Pravesh-
dc.contributor.authorKumar, Himanshu-
dc.contributor.authorMahadevan, Anjali-
dc.contributor.authorDevi, Sudha-
dc.contributor.authorRoy, Saonli-
dc.contributor.authorVenkataramani, Sugumar-
dc.date.accessioned2023-08-21T05:39:26Z-
dc.date.available2023-08-21T05:39:26Z-
dc.date.issued2021-
dc.identifier.citationChemistry – a European Journal, 27(10), 3463–3472.en_US
dc.identifier.urihttps://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202004620-
dc.identifier.urihttp://hdl.handle.net/123456789/4928-
dc.descriptionOnly IISER Mohali authors are available in the record.en_US
dc.description.abstractLight-responsive molecular systems with multiple photoswitches in C3-symmetric designs have enormous application potential. The design part of such molecular systems is critical due to its influence in several properties associated with the photoswitches. In order to tune, and in the evaluation of the design–property relationship, we synthesized 18 tripodal systems with variations in the core, linkers, connectivity, and azo(hetero)arene photoswitches. Through extensive spectroscopic and computational studies, we envisaged the factors controlling near-quantitative photoisomerization in both the directions (bistability) and the thermal stability of the metastable states. Furthermore, we also evaluated the impact of designs in obtaining reversible photo-responsive sol-gel phase transitions, solvatochromism, photo- and thermochromism.en_US
dc.language.isoen_USen_US
dc.publisherWileyen_US
dc.subjectC3-Symmetricen_US
dc.subjectMetastable Statesen_US
dc.titleTuning of Bistability, Thermal Stability of the Metastable States, and Application Prospects in the C3-Symmetric Designs of Multiple Azo(hetero)arenes Systemsen_US
dc.typeArticleen_US
Appears in Collections:Research Articles

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