C(sp3)–H Activation Enabled by (η3-Indolylmethyl)palladium Complexes: Synthesis of Monosubstituted Tetrahydrocarbazoles

Please use this identifier to cite or link to this item: http://hdl.handle.net/123456789/4958

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DC Field	Value	Language
dc.contributor.author	Kumar, Ketan	-
dc.contributor.author	Vivekanand, T.	-
dc.contributor.author	Singh, Bara	-
dc.contributor.author	Ramasastry, S. S. V.	-
dc.date.accessioned	2023-08-21T11:19:41Z	-
dc.date.available	2023-08-21T11:19:41Z	-
dc.date.issued	2021	-
dc.identifier.citation	Synthesis, 54(04), 943–952.	en_US
dc.identifier.uri	https://www.thieme-connect.de/products/ejournals/abstract/10.1055/a-1516-7960	-
dc.identifier.uri	http://hdl.handle.net/123456789/4958	-
dc.description	Only IISERM authors are available in the record.	en_US
dc.description.abstract	The synthesis of monosubstituted tetrahydrocarbazoles is achieved via the palladium-catalyzed formal [4+2] cycloaddition of 2-alkyl-3-indolylmethyl carbonates and monosubstituted olefins. The transformation demonstrates an unusual C(sp3)–H activation enabled by (η3-indolylmethyl)palladium complexes. The regioselectivity is found to be dependent on the nature of the substituent across the olefin component. Elaborate mechanistic studies are performed, and the synthetic utility of the products is also demonstrated.	en_US
dc.language.iso	en_US	en_US
dc.publisher	Thieme	en_US
dc.subject	C–H functionalization	en_US
dc.subject	tetrahydrocarbazoles	en_US
dc.title	C(sp3)–H Activation Enabled by (η3-Indolylmethyl)palladium Complexes: Synthesis of Monosubstituted Tetrahydrocarbazoles	en_US
dc.type	Article	en_US
Appears in Collections:	Research Articles

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