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http://hdl.handle.net/123456789/5102Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Singh, Kirti | - |
| dc.contributor.author | Singh, Rahul | - |
| dc.contributor.author | Adhikari, Debashis | - |
| dc.contributor.author | Hazarib, Arijit Singha | - |
| dc.date.accessioned | 2023-08-23T15:43:49Z | - |
| dc.date.available | 2023-08-23T15:43:49Z | - |
| dc.date.issued | 2022 | - |
| dc.identifier.citation | Chemical Communications, 58(27), 4384-4387. | en_US |
| dc.identifier.uri | DOI https://doi.org/10.1039/D2CC00397J | - |
| dc.identifier.uri | http://hdl.handle.net/123456789/5102 | - |
| dc.description | Only IISER Mohali authors are available in the record. | en_US |
| dc.description.abstract | A photoactive zinc β-diketiminate complex spans a wide redox window of 3.97 V at its excited state. Having a highly reducing excited-state potential, it generates an electrophilic trifluoromethyl radical by the reductive cleavage of triflyl chloride. This leads to trifluoromethylation of a set of arenes and heteroarenes. During the oxidative quenching of the photocatalyst, a ligand-centered radical cation is formed, which has been detected by spectroelectrochemical EPR measurement. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | Royal Society of Chemistry | en_US |
| dc.subject | Bimodal photocatalytic behaviour | en_US |
| dc.subject | zinc β-diketiminate | en_US |
| dc.subject | trifluoromethylation reactions | en_US |
| dc.title | Bimodal photocatalytic behaviour of a zinc β-diketiminate: application to trifluoromethylation reactions | en_US |
| dc.type | Article | en_US |
| Appears in Collections: | Research Articles | |
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|---|---|---|---|---|
| Need To Add…Full Text_PDF. | 15.36 kB | Unknown | View/Open |
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